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DOI: 10.1002/hlca.201300321 Full discussion of why the pK a of water (in water as solvent) should be 14.0 and the pKa of H3O(+) should be 0
20 Primarily, NADPH provides reducing equivalents for fatty acid synthase (FASN), the main rate-limiting enzyme, to synthesize fatty acids with acetyl-CoA serving as a primer and malonyl-CoA as a two-carbon donor, 21,22 and provides the needed electrons for ironsulfur (Fe/S) protein assembly that participate in non-essential amino acid biosynthesis and lipoic acid synthesis, tRNA modification, DNA replication and repair, and telomere maintenance
These discoveries have become integral to diagnosing hereditary epilepsy and have advanced the fields of personalized medicine and genetic counseling
Modulation of EMP-regulating pathways (AKT, AMPK, mTOR) provides additional therapeutic opportunities
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